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A study on oxygen transfer through wine corks was published in Science Advances.
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Thomas Karbowiak is a chemist at the University of Burgundy in France.
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Thomas Karbowiak is the senior author of the study.
Thomas Karbowiak, chemist
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"Twenty years ago, our group focused on the oxidation and aging of wine and all its parameters."
Thomas Karbowiak, chemist
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"Oxygen diffusion through cork stoppers is one of these parameters."
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Julie Chanut is a researcher at the University of Burgundy.
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The experimental setup consisted of small glass vials designed to mimic the cylindrical geometry of a commercial wine bottleneck.
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Each vial was sealed using scaled-down cork stoppers ranging in length from 6 to 42 millimeters.
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The interior of the vials was loaded with either gas or a specific volume of model wine.
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The team loaded half of the vials with wine and left the other half empty.
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The vials were sealed with corks of different lengths.
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The vials were filled with sensors.
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The vials were left for 18 months to age.
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Researchers identified four stages of oxygen transfer through the cork.
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The first phase of oxygen transfer lasted for the initial 15 days after the vials were corked.
Julie Chanut, researcher
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"It was an equilibration between the liquid phase of the model wine and the gas phase."
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During the first phase, oxygen dissolved in the liquid phase escaped back to the gas phase.
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During the first six months, the majority of oxygen entering the wine came from the cork itself.
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Oxygen diffused out of the microscopic spaces in the cork’s cellular structure.
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Vials sealed with longer corks received more oxygen because the larger corks contained more oxygen than shorter ones.
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Around four months into the experiment, the cork began to chemically interact with the wine.
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In vials where model wine was in contact with the cork, the liquid acted as a solvent extracting phenolic compounds from the cork.
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The extracted compounds included gallic acid, ellagic acid, and protocatechuic acid.
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The extracted compounds reacted with oxygen released from the outgassing cork, catalyzed by trace metals like iron and copper.
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The reaction caused a decrease in the wine’s oxygen content.
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After 15 months, the wine entered a fourth phase where oxygen from the outside environment steadily permeated through the cork.
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In the 18th month, the rate of oxygen transfer in vials sealed with corks longer than 30 millimeters was low.
Thomas Karbowiak, chemist
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"Because we used model wine in the experiment and focused on oxygen transfer, we didn’t do any tasting tests."
Thomas Karbowiak, chemist
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"Wine is a very particular case of a product without a shelf life."
Thomas Karbowiak, chemist
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"So, the question is, ‘When should I drink my wine?’"
Thomas Karbowiak, chemist
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"And actually, we are not able to answer this question."
Thomas Karbowiak, chemist
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"We need to know how much oxygen the wine should contain when it is optimal for tasting."
Thomas Karbowiak, chemist
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"If you have that information, you can select the stopper you need for the right preservation over a specific period of time to pinpoint the moment your wine is at its best."
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The study was published in Science Advances in 2026.
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The DOI for the study is 10.1126/sciadv.aed3023.
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